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Characterizing the degradation behavior of chemicals in the environment is a key component of chemical hazard and risk assessment. Persistence has been successfully characterized for readily and for slowly degradable chemicals using standardized tests, but for the third group of chemicals with intermediate degradability (“middle group”), the assessment is less straightforward. Whether chemicals of this group behave as persistent or not in a given environment depends on environmental factors such as the presence of sorbents that can limit the bioavailability of chemicals. 

This study, commissioned by DG Environment for the European Commission and produced by Wood and Ramboll.  The objective was to assess the use of PFASs and fluorine-free alternatives in textiles, upholstry, carpets, leather and apparel, including specific focus on volumes of use, technical function, and emissions.

Non-fluorine alternatives considered were hydrocarbons, silicones, dendrimers, polyurethane, nanomaterials, and alternative technologies.  The study makes recommendations for policy, including a REACH restriction on the placing on the market and use of these products that contain any PFAS, and a listing under the Stockholm Convention.  It is also recommended in the report that a restriction could be combined with voluntary industry measures and provisions in public procurement to encourage substitution of PFAS before mandatory legislation is introduced.